Plasticinjection part brittleness is caused most often by a loss of molecular weight
in the polymer material. A reduction in molecular weight results in a reduction
of the mechanical properties of the material, such as tensile strength,
elongation, and impact strength. Here are some causes and solutions below for Brittleness
of plastic injection parts.
Brittleness
from material degradation can be caused if materials are not dried
sufficiently. This applies specifically to hygroscopic materials. In this case,
a chemical reaction called hydrolysis takes place when materials are melted
with moisture present. When hydrolysis occurs, a loss in molecular weight
results in a reduction in physical properties.
Excessive
use of regrind can cause part brittleness since regrind has already been
exposed to heat and as a result suffers a loss in molecular weight.
Melt
temperatures may be higher than recommended process temperatures. In this case,
melt temperatures at the middle of the recommended melt temperature range
should be used.
The
molecular weight reduction is a result of material sitting in the barrel for
long periods of time, referred to as residence time. The BSR should fall
between 30 and 65%. If this falls well below 30%, this will indicate a
residence time problem that can lead to brittleness.
High
screw speeds and back pressure can overwork the material, resulting in an
increase in melt temperature.
Solutions: 1.The barrel-to-shot ratio (BSR) is
measurement, in terms of percentage, used in determining residence time. 2. A reduction in nozzle temperature will
reduce melt temperature avoiding brittleness form occurring. 3. Reducing screw
speed and lowering back pressure can prevent resin melt temperature. 4.Increasing
wall thickness, rib designs, avoidance of sharp corners, and addition of radii
can reduce the chance of brittle parts.
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